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Request PDF | On Jul 1, 2016, Gao Yuesheng and others published Selective flotation of scheelite from calcite: A novel reagent scheme | Find, read and cite all the research you need on ResearchGate
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1 day agoResults of binary mineral mixture flotation tests demonstrated that EA could well achieve the selective separation of scheelite from calcite. Moreover, the industrial test results ( Table 2 ) of the actual scheelite in Luanchuan showed that the concentrate grade was improved from 24.66% to 28.26% and the concentrate recovery was increased from ...
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Use of Al2(SO4)3 and acidified water glass as mixture depressants in flotation separation of fluorite from calcite and celestite: Jia Tian · Longhua Xu · Wei Sun · Xiaobo Zeng · Shuai Fang · Haisheng Han · Kai Hong · Yuehua Hu: Selective breakage of mineralised synthetic particles by high voltage pulses.
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Overall, the greenest, most efficient, and cheapest method for scheelite flotation is to use fatty acids as collectors with sodium silicate as depressant, although this solution suffers from a crucial lack of selectivity regarding the calcium salts, namely fluorite, calcite, and apatite.
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A scheelite concentrate is recovered from a scheelite ore containing silicate minerals and other calcareous minerals by froth flotation which process comprises grinding the ore sufficiently fine to liberate the scheelite grains, pulping the gound ore with water to form a slurry containing between about 20% and about 40% solids by weight, sequentially conditioning the slurry with at least one ...
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Powder XRD data confirm that the purities of scheelite, fluorite, and calcite minerals are higher than 97%. The fractions finer than 74 μm were used for flotation experiments. Analytical grade BHA and lead nitrate were purchased from Guangfu, Tianjin, China. The pH was adjusted with NaOH or HCl stock solutions.
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Fa K Q, Nguyen A V, Miller J D. Interaction of calcium dioleate collector colloids with calcite and fluorite surfaces as revealed by AFM force measurements and molecular dynamics simulation. ... N-((hydroxyamino)-alkyl) alkylamide surfactants for scheelite/calcite flotation separation. J Ind Eng Chem, 2016, 33:131 ... of calcite and apatite ...
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Calcite flotation was poorer than scheelite in pH range 7 to 11 and scheelite flotation after reaching a maximum around pH 9, decreased with further increase in pH falling from 95 % to 20% at pH 12. Calcite flotation tending to- wards a minimum at pH 9, good separation of the minerals should be possible in the pH range 9-10.
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calcite are similar due to that fact that they both belong to carbonate minerals. NaOL has been widely used in the flotation of semisoluble salt-type minerals, such as scheelite, calcite, fluorite, barite, and celestite (Martinez et al., 2003, Li and Gao, 2018 and 2017; Gao et al., 2018a), showing a pronounced
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Hallimond flotation test of apatite, calcite and fluorite 3.1.1. Effect of concentration (ranging from 5µM to 1000µM) at a constant pH of 9.2 Results from flotation experiments for apatite can be seen in Figure 2 (apa-c). Even at the moderate concentration of 600mM, apatite was floated efficiently ( 80%) with C12MalNa
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Bench scale laboratory flotation tests suggest that better dispersion leads to a diminished interaction of chalcopyrite with gangue. The improved Cu grade and recovery then are likely in response to an increased accessibility to collector along with a linked increase in particle bubble attachment resulting in better separation efficiency.
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comprehensive study and concluded that "the depression of the calcium minerals (calcite, scheelite, and fluorite) is only related to the selective dissolution of calcium ions by the phosphates, but not related to the adhesion of the phosphates on the mineral surface".
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The U.S. Department of Energy's Office of Scientific and Technical Information
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In ore deposits, scheelite always coexists with other calcium-containing minerals such as calcite and fluorite. Owing to the same Ca active sites on their cleavage planes ( Rai et al., 2002 ), the commonly used fatty acid anionic collector, such as sodium oleate, can strongly collect all of them and exhibit little selectivity.
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Flotation Scheelite Calcite Fluorite 1. Introduction Scheelite (CaWO 4) is a typical tungstate mineral and usually co-exists with other calcium-containing minerals, such as calcite (CaCO 3) and fluorite (CaF 2)indeposit.Bynow,flotation is the most commonly used technique to separate scheelite from calcite and fluorite. Long
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An excellent frother for selective flotation of metallics and non-metallics. Produces a brittle forth. ... Promoter and collector for scheelite and other tungsten minerals. Orthotoluidine: A brownish black liquid. Very fluid. ... Calcite depressant when floating fluorite with fatty acids. Xanthate Z-3: C2H3OCSSK. Potassium ethyl xanthate ...
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Oleoyl sarcosine is used as a selective collector both in the flotation of fluorite in calcitic gangue [52] and of scheelite in siliceous gangue [19], [53]. Its selectivity for scheelite against other calcium-bearing minerals is limited [53] but still greater than sodium oleate [54].
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Selective flotation of scheelite from calcite: A novel reagent scheme. Y Gao, Z Gao, W Sun, Y Hu. International Journal of Mineral Processing 154, 10-15, 2016. 139: ... Reverse flotation separation of fluorite from calcite: a novel reagent scheme. J Wang, Z Zhou, Y Gao, W Sun, Y Hu, Z Gao. Minerals 8 (8), 313, 2018. 24:
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The separation of scheelite (CaWO 4) from calcite (CaCO 3) proves to be quite difficult given the physical and chemical similarities that both minerals share—including hardness, solubility, and specific gravity [8]. Thus, flotation was researched as a means for the selective recovery of scheelite.
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Gao Z Y, Sun W, Hu Y H. New insights into the dodecylamine adsorption on scheelite and calcite:an adsorption model. Miner Eng, 2015, 79:54 [6] Santos E P, Dutra A J B, Oliveira J F. The effect of jojoba oil on the surface properties of calcite and apatite aiming at their selective flotation. Int J Min Process, 2015, 143:34 [7]
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Various reagents suitable for scheelite flotation (collectors and depressants, mostly) are reviewed in the present work, with a strong focus on the separation of scheelite from calcium salts, namely, fluorite, apatite, and calcite, which generally represent significant amounts in tungsten skarns.
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Scheelite sorting method can re-election, magnetic separation, flotation. Different types and nature of the ore beneficiation methods and processes used are different. But based on scheelite good floatability, more due to the presence in the ore of a similar nature to their gangue minerals calcium, which led to the flotation of complexity
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A study on selective flotation in low and high pyritic copper sulphide ores. by Ahmad Hassanzadeh. Download Free PDF Download PDF Download Free PDF View PDF. The Behaviour of Mixtures of Sodium Iso-Butyl Xanthate and Sodium Di-Ethyl Dithiophosphate during the Flotation of a Cu-Ni-Pt Ore in Degrading Water Quality.
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The distribution feature and the number of broken bonds of exposed active ions (such as Ca2+ for fluorite) can be used to predict and explain the anisotropic surface wettability and surface charge, as well as the adsorption mode and strength of organic molecule binding to different exposed surfaces. The calculation of surface broken bonds can ...
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the self-assembly mechanism of the flotation agent and its inhibition mechanism on quartz. Jiao et al. [22] used a multi-confectionery gel to separate scheelite and calcite by flotation separation. The carboxyl group on the molecular chain of the pectin chemically chelated with the calcium ion on the calcite surface and adsorbed on the calcite ...
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Score: 4.1/5 (25 votes) . It is found chiefly in Sweden, Norway, Germany, Cornwall, England, Canada, La Cobaltera, Chile, Australia, the Democratic Republic of the Congo, and Morocco.Cobaltite can be separated from other minerals by selective, pH controlled, flotation methods, where cobalt recovery usually involves hydrometallurgy.
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Sodium silicate is one of the main depressants against calcite and fluorite in the scheelite flotation industry. In the first part of this article, the authors acidified sodium silicate (AWG) with . Expand
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Selective flotation of scheelite from calcite using xanthan gum as depressant. Miner. Eng., 138 (2019), pp. 14-23. Article Download PDF View Record in Scopus Google ... Differential adsorption of hydrolytic polymaleic anhydride as an eco-friendly depressant for the selective flotation of apatite from dolomite. Sep. Purif. Technol., 256 (2021 ...
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A process for beneficiating celestite, barite, scheelite, fluorite, calcite, magnetite, gypsum, anhydrite, and apatite is disclosed comprising froth floating a ground pulp conditioned with gangue depressant using tetrasodium N-(1,2-dicarboxyethyl)N-octadecylsulfosuccinamate as collector. ... 238000005188 flotation Methods 0.000 title ...
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An important domestic resource beneficiation problem is the selective flotation of scheelite from the skarn type of deposit. Here the scheelite is associated with fluorite and much limestone and marble. ... quebracho is rarely used to depress calcite during scheelite flotation because, even in carefully controlled additions, it tends to depress ...
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fluorite. calcite, apatite and scheelite are impor-tant raw materials for chemical. cement. fertilizer and metallurgical industries. These minerals are beneficiated by flotation using oleic acid/sodium oleate as collector. The individual occurrence of these minerals in pure state is very rare and they are mostly available as a mixture of calcium
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Under flotation conditions using anionic fatty acid (Acintol FA-1 tall oil) with varying modifiers—SHMP, tetrasodium pyrophosphate (TSPP), and CMC in neutral to alkalinic region (pH 6-12) float dolomite and sink magnesite—Matis et al. 1988 suggested that selective separation can be further improved in several flotation stages [15].
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Fluorite particles as a novel calcite recovery depressant in scheelite flotation using Pb-BHA complexes as collectors. ... The effect of polyacrylic acid on the surface properties of calcite and fluorite aiming at their selective flotation. C Zhang, Z Gao, Y Hu, W Sun, H Tang, Z Yin, J He, Q Guan, Y Zhu.
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in this study, the polyacrylic acid (paa) was studied as a selective depressant for calcite in the selective flotation of fluorite and calcite, and the implications of this process for the separation of fluorite ore were studied using micro-flotation tests, and the results were analyzed with fourier transform infrared spectroscopy (ft-ir) and .
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1. Introduction. Scheelite (CaWO 4) is an important mineral for extracting tungsten and usually associated with fluorite in Chinese scheelite deposits. 1,2 The utilization of refractory scheelite deposits—wolframite resources that can be easily separated via the gravity method and are almost depleted—has become important. Conventional flotation practice for separating scheelite from ...
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Selective adsorption of tannic acid (TA) on calcite surfaces and the implications of this process for the separation of fluorite ore were studied by microflotation tests, surface adsorption experiments, zeta potential measurements, UV-vis analysis, and X-ray photoelectron spectroscopy (XPS) analysis. The microflotation tests indicated that TA, when added before sodium oleate (NaOl), could ...
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calcite flotation mineral concentrate scheelite Prior art date 1962-12-17 Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.) Expired - Lifetime Application number US245207A Inventor Burwell Blair Original ...
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